The Space of Physical Frameworks (Part 3)
Posted by John Baez
In Part 1, I explained how statistical mechanics is connected to a rig whose operations depend on a real parameter and approach the ‘tropical rig’, with operations and , as . I explained my hope that if we take equations from classical statistical mechanics, expressed in terms of this -dependent rig, and let , we get equations in thermodynamics. That’s what I’m slowly trying to show.
As a warmup, last time I explained a bit of thermodynamics. We saw that some crucial formulas involve Legendre transforms, where you take a function and define a new one by
I’d like the Legendre transform to be something like a limit of the Laplace transform, where you take a function and define a new one by
Why do I care? As we’ll see later, classical statistical mechanics features a crucial formula that involves a Laplace transform. So it would be great if we could find some parameter in that formula, take the limit , and get a corresponding equation in thermodynamics that involves a Legendre transform!
As a warmup, let’s look at the purely mathematical question of how to get the Legendre transform as a limit of the Laplace transform — or more precisely, something like the Laplace transform. Once we understand that, we can tackle the physics in a later post.
From Legendre to Laplace: the rough idea
In Part 1 we saw that for each we can make into a rig with addition
As , this operation approaches
and we get a version of the tropical rig. (There’s a more popular version using instead of , but I decided to use .)
Suppose we want to define a notion of integration with replacing ordinary addition. We could call it ‘-integration’ and denote it by . Then it’s natural to try this:
If the function is nice enough, we could hope that
Then, we could hope to express the Legendre transform
as the limit of some transform involving -integration.
Indeed, in Section 6 here, Litvinov claims that the Legendre transform is the analogue of the Laplace transform:
- Grigory L. Litvinov, Tropical mathematics, idempotent analysis, classical mechanics and geometry.
But he doesn’t state any result saying that it’s a limit of the Laplace transform, or something like that.. Touchette states a result along these lines here:
- Hugo Touchette, Legendre–Fenchel transforms in a nutshell.
He even applies it to classical statistical mechanics! But he’s operating as a physicist, not a mathematician, so he doesn’t state a precise theorem. I’d like to take a crack at that, just to be sure I’m not fooling myself.
The Legendre transform as a limit
Touchette’s formula gives an Legendre transform involving a sup rather than an inf. I slightly prefer a version with an inf. We’ll get the Legendre transform as a limit of something that is not exactly a Laplace transform, but close enough for our physics application:
Almost Proved Theorem. Suppose that is a concave function with continuous second derivative. Suppose that for some the function has a unique minimum at , and . Then as we have
Almost Proof. Laplace’s method should give the asymptotic formula
Taking the logarithm of both sides and dividing by we get
since
Since has a minimum at we get the desired result:
The only tricky part is that Laplace’s method as proved here requires finite limits of integration, while we are integrating from all the way up to . However, the function is concave, with a minimum at , and it has positive second derivative there since . Thus, it grows at least linearly for large , so as the integral
can be arbitrarily well approximated by an integral over some finite range . ∎
Someone must have studied the hell out of this issue somewhere — do you know where?
Now, let’s look at the key quantity in the above result:
We’ve got a and then the logarithm of an integral that is not exactly a Laplace transform… but it’s close! In fact it’s almost the Laplace transform of the function
since
The right hand side here would be the Laplace transform of if it weren’t for that in the exponential.
So, it seems to be an exaggeration to say the Legendre transform is a limit of the Laplace transform. It seems to be the limit of something that’s related to a Laplace transform, but more complicated in a number of curious ways.
This has made my life difficult (and exciting) for the last few weeks. Right now I believe that all the curious complications do exactly what we want them to in our physics applications. But I should hold off on declaring this until I write up all the details: I keep making computational mistakes and fixing them, with a roller-coaster of emotions as things switch between working and not working.
Re: The Space of Physical Frameworks (Part 3)
David Corfield may be happy to hear that I’m finally answering his question from April 2014:
Igor Khavkine’s reply to that question was spot on, since Laplace’s method is a cousin to the saddle point or steepest descent method. But there seem to be some subtleties… which I’m tackling now.